3,3′-(1-Oxopropane-1,3-diyl)bis(1,3-thiazolidine-2-thione) chlorobenzene hemisolvate
نویسندگان
چکیده
The title compound, C9H12N2OS4·0.5C6H5Cl, which contains two 1,3-thia-zolidine-2-thione rings, is a by-product of the synthesis of 3-acryloyl-1,3-thia-zolidine-2-thione. The dihedral angle between these rings is 79.95 (9)°, with both rings displaying a twisted conformation. The twist angle of the amide group is 5.6 (1)°. In the crystal, the molecules are linked into [001] chains by C-H⋯O interactions. The chloro-benzene solvent mol-ecule was found to show unresolvable disorder about a centre of inversion and its contribution to the scattering was removed with the SQUEEZE option in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155].
منابع مشابه
[μ-3,3′-Diisopropyl-1,1′-(propane-1,3-diyl)bis(1,3-diazinan-2-ylidene)]bis[bromido(η4-cycloocta-1,5-diene)rhodium(I)]
The title compound, [Rh2Br2(C8H12)2(C17H32N4)], was obtained by the reaction of 3,3'-(propane-1,3-di-yl)bis-(1-isopropyl-3,4,5,6-tetra-hydro-pyrimidin-1-ium) bromide and [{Rh(cod)Cl}2] (cod is cyclo-octa-1,5-diene) in tetra-hydro-furan. The two Rh(I) atoms each have a distorted square-planar coordination environment, defined by a bidentate cod ligand, a bromide anion and one C atom of the bridg...
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The asymmetric unit of the title compound, C(8)H(8)N(2)O(4)S(2), contains one half of a centrosymmetric mol-ecule. A short C⋯O distance of 3.012 (4) Å between the carbonyl groups of neighbouring mol-ecules indicates the presence of dipole-dipole inter-actions. The crystal packing exhibits also weak inter-molecular O⋯S [3.239 (3) Å] and C-H⋯O inter-actions.
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